By focusing on the step-by-step logic—calculating the precipitation threshold for each ion and determining the concentration remaining—the concepts in the fractional precipitation POGIL module become much clearer.
When looking at a model answer key for these
[Ag+]=1.8×10-100.10 M=1.8×10-9 Mopen bracket cap A g raised to the positive power close bracket equals the fraction with numerator 1.8 cross 10 to the negative 10 power and denominator 0.10 M end-fraction equals 1.8 cross 10 to the negative 9 power M Step 2: Calculate required to precipitate Ag2CrO4cap A g sub 2 cap C r cap O sub 4 fractional precipitation pogil answer key
) of one specific salt is exceeded, causing it to fall out of solution while others remain dissolved. 2. Predicting the First Precipitate
In many versions of this POGIL, the initial model explores separating Zn2+cap Z n raised to the 2 plus power Cu2+cap C u raised to the 2 plus power ions using sodium carbonate ( Na2CO3cap N a sub 2 cap C cap O sub 3 : Solution A : Contains Zinc Nitrate and Copper(II) Nitrate. Solution B : Sodium Carbonate ( Na2CO3cap N a sub 2 cap C cap O sub 3 ), which provides the CO32−cap C cap O sub 3 raised to the 2 minus power ions needed for precipitation. Predicting the First Precipitate In many versions of
[Ag+]required for Ag2CrO4=Ksp(Ag2CrO4)[CrO42−]open bracket Ag raised to the positive power close bracket sub required for Ag sub 2 CrO sub 4 end-sub equals the square root of the fraction with numerator cap K sub s p end-sub open paren Ag sub 2 CrO sub 4 close paren and denominator open bracket CrO sub 4 raised to the 2 minus power close bracket end-fraction end-root Step 3: Identify the First Precipitate Compare the two calculated values for
If a solution already contains a high concentration of Cl⁻ ions (e.g., 1.0 M), how does this affect the solubility of AgCl compared to pure water? Calculate the molar solubility in each case. Calculate the molar solubility in each case
This sequential separation process relies strictly on the solubility product constant ( Kspcap K sub s p end-sub ) of the potential precipitates. Key Factors for Successful Separation The separation is cleanest when the Kspcap K sub s p end-sub
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will precipitate first because it requires a much lower concentration of Ag+Ag raised to the positive power ions to exceed its solubility limit. Part 2: Calculating the Threshold Concentration What concentration of Ag+Ag raised to the positive power is required to initiate the precipitation of each ion?